郑强;史洪刚;冯宏伟;刘全利;刘铁;

• 1:中国兵器科学研究院宁波分院
• 2:浙江大学材料科学与工程系
• 3:晋西工业集团冲压分厂

摘要(Abstract)：

块体金属玻璃有许多优良的性能,如高强度、高硬度、高比强度、好的耐腐蚀抗力以及优良的软磁性能等。然而,近乎于零的室温塑性应变严重限制了其作为结构材料的实际应用。总结了近年来改善块体金属玻璃室温脆性的最新研究进展,并对这些方法的优缺点进行了分析。

关键词(KeyWords)： 块体金属玻璃;非晶材料;复合材料;断裂韧性;力学特性

Abstract:

Keywords:

基金项目(Foundation): 第51批中国博士后科学基金面上资助项目(2012M511390);; 宁波市自然科学基金(2012A610102);; 中国兵器科学研究院宁波分院风险基金项目

作者(Author): 郑强;史洪刚;冯宏伟;刘全利;刘铁;

Email:

DOI:

参考文献(References)：

• [1]Peker A,Johnson W L.A highly processable metallic glass:Zr 41.2 Ti 13.8 Cu 12.5 Ni 10.0 Be 22.5[J].Appl Phys Lett,1993,63:2342-2344.
• [2]Lou H B,Wang X D,Xu F,et al.73mm diameter bulk metal lic glass rod by copper mould casting[J].Appl Phys Lett,2011,99:051910.
• [3]Inoue A,Nishiyama N,Kimura H.Preparation and thermal sta bility of bulk amorphous Pd 40 Cu 30 Ni 10 P 20 alloy cylinder of72mm in diameter[J].Mater Trans JIM,1997,38:179-185.
• [4]Schroers J,Johnson W L.Highly processable bulk metallic glass forming alloys in the Pt Co Ni Cu P system[J].Appl Phys Lett,2004,84:3666-3668.
• [5]Shen Y,Ma E,Xu J.A group of Cu(Zr)based BMGs with criti cal diameter in the range of12to18mm[J].J Mater Sci Tech,2008,24:149-152.
• [6]Guo F Q,Wang H J,Poon S J,et al.Ductile titanium based glassy alloy ingots[J].Appl Phys Lett,2005,86:091907.
• [7]Zheng Q,Xu J,Ma E.High glass forming ability correlated with fragility of Mg Cu(Ag)Gd alloys[J].J Appl Phys,2007,102:113519.
• [8]Shen J,Chen Q J,Sun J F,et al.Exceptionally high glass form ing ability of an FeCoCrMoCBY alloy[J].Appl Phys Lett,2005,86:151907.
• [9]Jiang Q K,Zhang G Q,Yang L,et al.La based bulk metallic glasses with critical diameter up to30mm[J].Acta Mater,2007,55:4409-4418.
• [10]Schroers J,Lohwongwatana B,Johnson W L,et al.Gold based bulk metallic glass[J].Appl Phys Lett,2005,87:061912.
• [11]Guo F Q,Poon S J,Shiflet G J.Metallic glass ingots based on yttrium[J].Appl Phys Lett,2003,83:2575-2577.
• [12]Zeng Y Q,Nishiyama N,Wada T,et al.Ni rich Ni Pd P glassy alloy with high strength and good ductility[J].Mater Trans JIM,2006,47:175-178.
• [13]Park E S,Kim D H.Formation of Ca Mg Zn bulk glassy alloy by casting into cone shaped copper mold[J].J Mater Res,2004,19:685-688.
• [14]Zhang L,Ma E,Xu J.Hf based bulk metallic glasses with crit ical diameter on centimeter scale[J].Intermetallics,2008,16:584-586.
• [15]Men H,Pang S J,Zhang T.Effect of Er doping on glass form ing ability of Co 50 Cr 15 Mo 14 C 15 B 6 alloy[J].J Mater Res,2006,21:958-961.
• [16]Zhang B,Zhao D Q,Pan M X,et al.Formation of cerium based bulk metallic glasse[J].Acta Mater,2006,54:3025-3032.
• [17]Spaepen F.Microscopic mechanism for steady state inhomo geneous flow in metallic glasses[J].Acta Metall,1976,25:407-415.
• [18]Wright W J,Schwarz R B,Nix W D.Localized heating during serrated plastic flow in bulk metallic glasses[J].Mater Sci Eng A,2001,319:229-232.
• [19]Kato H,Inoue A.Synthesis and mechanical properties of bulk amorphous Zr Al Ni Cu alloy containing ZrC particles[J].Mater Trans JIM,1997,38:793-800.
• [20]Choi Yim H,Johnson W L.Bulk metallic glass matrix com posites[J].Appl Phys Lett,1997,71:3808-3810.
• [21]Choi Yim H,Busch R,K ster U,et al.Synthesis and charac terization of particulate reinforced Zr 57 Nb 5 Al 10 Cu 15.4 Ni 12.6 bulkmetallic glass composites[J].Acta Mater,1999,47:2455-2462.
• [22]Choi Yim H,Conner R D,Szuecs F,et al.Processing,micro structure and properties of ductile metal particulate rein forced Zr 57 Nb 5 Al 10 Cu 15.4 Ni 12.6 bulk metallic glass composites[J].Acta Mater,2002,50:2737-2745.
• [23]Conner R,Dandliker R B,Johnson W L.Mechanical proper ties of tungsten and steel fiber reinforced Zr 57 Nb 5 Al 10 Cu 15.4 Ni 12.6 bulk metallic glass composite[J].Acta Mater,1998,46:6089-6102.
• [24]Xu Yingkun,Ma Han,Xu Jian,et al.Mg based bulk metallic glass composites with plasticity and gigapascal strength[J].Acta Mater,2005,53:1857-1866.
• [25]Pan D G,Zhang H F,Wang A M,et al.Enhanced plasticity in Mg based metallic glass composite reinforced with ductile Nb particles[J].Appl Phys Lett,2006,89:261904.
• [26]Jang J S C,Ciou J Y,Huang T H,et al.Enhanced mechanical performance of Mg metallic glass with porous Mo particles[J].Appl Phys Lett,2008,92:011930.
• [27]Kinata M,Kato H,Hasegawa M,et al.High specific strength Mg based bulk metallic glass matrix composite highly duc tilized by Ti dispersoid[J].Mater Sci Eng A,2008,494:299-303.
• [28]Szuecs F,Kim C P,Johnson W L.Mechanical properties of Zr 56.2 Ti 13.8 Nb 5.0 Cu 6.9 Ni 5.6 Be 12.5 ductile phase reinforced bulk me tallic glass composite[J].Acta Mater,2001,49:1507-1513.
• [29]Hays C C,Kim C P,Johnson W L.Microstructure controlled shear band pattern formation and enhanced plasticity of bulk metallic glass containing in situ formed ductile phase den drite dispersions[J].Phys Rev Lett,2000,84:2901-2904.
• [30]Ma H,Shi L L,Xu J,et al.Chill cast in situ composites in the pseudo ternary Mg(Cu,Ni)Y glass forming system:micro structure and compressive properties[J].J Mater Res,2007,22:314-325.
• [31]Hui X,Dong W,Chen G L,et al.Formation,microstructure and properties of long period order structure reinforced Mg based bulk metallic glass composites[J].Acta Mater,2007,55:907-920.
• [32]Hofmann D C,Suh J Y,Wiest A,et al.Designing metallic glass matrix composites with high toughness and tensile duc tility[J].Nature,2008,451:1085-1090.
• [33]Lewandowki J J,Wang W H,Greer A L.Intrinsic plasticity or brittleness of metallic glasses[J].Philos Mag Lett,2005,85:77-87.
• [34]Chen H S,Krause J T,Coleman E.Elastic constants,hard ness and their implications to flow properties of metallic glass es[J].J Non Cryst Solids,1975,18:157-171.
• [35]Schroers J,Johnson W L.Ductile bulk metallic glass[J].Phys Rev Lett,2004,93:255506.
• [36]Liu Y H,Wang G,Wang R J,et al.Super plastic bulk metal lic glasses at room temperature[J].Science,2007,315:1385-1388.
• [37]Johnson W L,Samwer K.A universal criterion for plastic yielding of metallic glass with a(T/Tg)2/3 temperature depen dence[J].Phys Rev Lett,2005,95:195501.
• [38]Song S X,Bei H,Wadsworth J,et al.Flow serration in a Zr based bulk metallic glass in compression at low strain rate[J].Intermetallics,2008,16:813-818.
• [39]Conner R D,Johnson W L.Composition dependent ductility in the amorphous Zr Ti Ni Cu Be system[J].Scripta Mater,2006,55:645-648.
• [40]Yao K F,Zhang C Q.Fe based bulk metallic glass with high plasticity[J].Appl Phys Lett,2007,90:061901.
• [41]Park B J,Chang H J,Kim W T,et al.In situ formation of two amorphous phases by liquid phase separation in Y Ti Al Co alloy[J].Appl Phys Lett,2004,85:6353-6355.
• [42]Du X H,Huang J C,Hsieh K C,et al.Two glassy phase bulk metallic glass with remarkble plasticity[J].Appl Phys Lett,2007,91:131901.
• [43]Park E S,Kim D H.Phase separation and enhancement o plasticity in Cu Zr Al Y bulk metallic glasses[J].Acta Ma ter,2006,54:2597-2604.
• [44]Brothers A H,Dunand D C.Ductile bulk metallic glass foams[J].Adv Mater,2005,17:484-486.
• [45]Lee M H,Sordelet D J.Synthesis of bulk metallic glass foam by powder extrusion with a fugitive second phase[J].App Phys Lett,2006,88:021921.
• [46]Wada T,Inoue A,Greer A L.Enhancement of room tempera ture plasticity in a bulk metallic glass by finely dispersed po rosity[J].Appl Phys Lett,2005,86:251907.
• [47]Demetriou M D,Duan G,Veazey C,et al.Amorphous Fe based metal foam[J].Scripta Mater,2007,57:9-12.
• [48]Xie G Q,Zhang W,Louzguine Luzgin D V,et al.Microstruc ture and mechanical properties of porous Zr 55 Cu 30 Al 10 Ni 5 bulk metallic glass fabricated by spark plasma sintering proces[J].Mater Trans JIM,2007,48:1589-1594.
• [49]Brothers A H,Dunand D C,Zheng Q,et al.Amorphous Mg based metal foams with ductile hollow spheres[J].J App Phys,2007,102:023508.
• [50]Zhang H F,Wang A M,Li H,et al.Quasi static compressive property of metallic glass/porous tungsten bi continuous phase composite[J].J Mater Res,2006,21:1351-1354.
• [51]Chen Y L,Wang A M,Zhang H F,et al.Preparation and char acterization of amorphous alloy/porous SiC bi continuous structure composite[J].Int J Mod Phys B,2009,23:1294-1299.
• [52]Xue Y F,Cai H N,Wang L,et al.Dynamic compressive defor mation and failure behavior of Zr based metallic glass rein forced porous tungsten composite[J].Mater Sci Eng A,2007,445:275-280.
• [53]Xue Y F,Cai H N,Wang L,et al.Strength improved Zr based metallic glass/porous tungsten phase composite by hy drostatic extrusion[J].Appl Phys Lett,2007,90:081901.
• [54]Sun Y,Zhang H F,Wang A M,et al.Mg based metallic glass/titanium interpenetrating phase composite with high mechani cal performance[J].Appl Phys Lett,2009,95:171910.